Experimental Validation of an Affinity Energy Distribution Calculated with the Expectation Maximization Method
- 1 July 2004
- journal article
- Published by American Chemical Society (ACS) in Langmuir
- Vol. 20 (16) , 6521-6523
- https://doi.org/10.1021/la040023h
Abstract
The difference between the average energies of the high-energy modes of the adsorption energy distributions of (S)-alprenolol and (R)-alprenolol on a chiral stationary phase calculated by the expectation maximization method agree well with the difference between the adsorption energies of these two compounds measured by isothermal titration calorimetry.Keywords
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