Fluorescence Spectrum and Relaxation Time Measurement of Cs2UO2Br4
- 15 March 1972
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 56 (6) , 2838-2843
- https://doi.org/10.1063/1.1677614
Abstract
Fluorescence spectra of Cs2UO2Br4 were studied at 14, 4.2, and 1.4°K. Raman spectrum and relaxation times were also measured. At low temperatures, the fluorescence spectra showed additional lines which had highly temperature‐dependent relative intensities. These lines are thought of as originating from dislocations of the uranyl complex. The problem of parity of the first excited electronic state of the uranyl ion is also discussed.Keywords
This publication has 10 references indexed in Scilit:
- The low frequency infrared and Raman spectroscopic studies of some uranyl complexes: the deformation frequency of the uranyl ionCanadian Journal of Chemistry, 1970
- Vibrational spectra of the [UO2Cl4]2− and the [UO2Br4]2− ionsSpectrochimica Acta Part A: Molecular Spectroscopy, 1969
- Absorption Spectrum of Np in UPhysical Review B, 1969
- A vibronic analysis of the absorption spectrum of the uranyl ionSpectrochimica Acta Part A: Molecular Spectroscopy, 1969
- Near-Visible Absorption Spectra of the CsUO2(NO3) CrystalThe Journal of Chemical Physics, 1967
- Harmonic Franck—Condon Overlap Integrals Including Displacement of Normal CoordinatesThe Journal of Chemical Physics, 1964
- Fine structure of the electronic absorption spectra of uranyl compoundsSpectrochimica Acta, 1962
- THE ABSORPTION SPECTRUM OF BO2Canadian Journal of Physics, 1961
- The electronic structure, spectra, and magnetic properties of actinyl ionsJournal of Molecular Spectroscopy, 1961
- Fluorescent Lifetimes of Uranyl Salts at Different Temperatures*Journal of the Optical Society of America, 1957