Carbon-skeleton rearrangement of the alkyl ligand in a vitamin B12 derivative
- 1 January 1976
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 988-989
- https://doi.org/10.1039/c39760000988
Abstract
Cyclopropylmethylcobalamin is isomerised to but-3-enylcobalamin in solution at 60 °C and in the presence of oxygen at a rate which is virtually independent of the dielectric constant of the solvent.Keywords
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