On the Lower Boiling Product of Silicon-methylchloride Reaction
- 1 February 1956
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 29 (2) , 236-241
- https://doi.org/10.1246/bcsj.29.236
Abstract
(1) Tetramethylsilane, dimethylchlorosilane and methyldichlorosilane and a small amounts of trichlorosilane and hydrocarbon by-product were found in the lower boiling product (b. p. 26°–40°C) of silicon methylchloride reaction. (2) Dimethylethoxysilane and methyldiethoxysilane besides small amounts of dimethyldiethoxysilane and triethoxysilane were found in the ethanolysis product. (3) Owing to the contamination of the hydrocarbon by-product, dimethylchlorosilane could not be isolated by repeated distillation. To characterize this substance, it was synthesized from dimethylethoxysilane and benzoylchloride. (4) By hydrolysis, linear copolymers M′Dn′M′ and M′DnM′ were found. Of these, copolymers M′Dn′M′ having two to eight silicon atoms and M′DM′ have been characterized.This publication has 12 references indexed in Scilit:
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