Thermal explosions and the linear mixture rule
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 84 (1) , 35-40
- https://doi.org/10.1039/f29888400035
Abstract
The results of measurements of thermal explosions for mixtures of methyl isocyanide with ethyl isocyanide diethylmercury and di-t-butyl peroxide in spherical vessels near 350 °C are reported. Although the linear mixture rule holds quite well with ethyl isocyanide, it appears to fail mildly for diethylmercury; in the case of di-t-butyl peroxide too much reaction occurs in the inlet to the reaction vessel for a test of the rule to be made. Approximate measurements of the thermal conductivities for ethyl isocyanide and diethylmercury are reported.Keywords
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