The Impact of the Donor-Acceptor Concept
- 1 April 1982
- journal article
- research article
- Published by Taylor & Francis in Comments on Inorganic Chemistry
- Vol. 1 (5) , 265-278
- https://doi.org/10.1080/02603598208078098
Abstract
The rules of the extended donor-acceptor concept are reviewed and applied to interactions between molecules in the gas phase as well as in the solid and liquid states. The applicability of the rules to interactions in solution and at phase boundaries is pointed out. By applying these rules to phenomena in microscopic areas, the different parts of a molecular system are ordered from the point of view of their significance for the whole system under consideration. In this way the concept of “hierarchic order” has been developed and found to be universally applicable to molecular systems. The consequences for the acquisition of new knowledge in all branches of molecular science are indicated, and the continuum model of matter is states as one of the basic requirements of the hierarchically ordered relationships.Keywords
This publication has 25 references indexed in Scilit:
- Non-statistical approach to solutionsPure and Applied Chemistry, 1981
- Lösungsmittel‐ und Salzeffekte auf das Redoxpotential des Systems Tris(äthylendiamin)kobaltat(III/II)Zeitschrift für anorganische und allgemeine Chemie, 1980
- Molekulare SystemeZeitschrift für Chemie, 1979
- Influence of the Local Surface Structure on thePhotoemission of Adsorbed XenonPhysical Review Letters, 1979
- The extension of the donor-acceptor conceptPublished by Walter de Gruyter GmbH ,1979
- A semiempirical model for the description of solvent effects on chemical reactionsPublished by Walter de Gruyter GmbH ,1979
- Correlation of solvent effects on rates of solvolysis and SN2 reactionsThe Journal of Organic Chemistry, 1978
- Thermodynamik von Legierungsschmelzen: Meßmethoden und ErgebnisseBerichte der Bunsengesellschaft für physikalische Chemie, 1977
- Empirical parameters for donor and acceptor properties of solventsElectrochimica Acta, 1976
- Betrachtungen zu den Kristallstrukturen von Elektronen‐Donor‐Acceptor‐KomplexenAngewandte Chemie, 1968