Cobalt to oxygen migration of the trimethylsilyl group in trimethylsilylcobalt tetracarbonyl
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 497-498
- https://doi.org/10.1039/c39730000497
Abstract
When Me3Si–Co(CO)4 is heated at 105° for 50 h, migration of the Me3Si group from cobalt to oxygen takes place to give Me3SiOCCo3(CO)9 and (Me3SiOC)4Co2(CO)4; the former compound is also formed in high yields within an hour at room temperature by the reaction of Me3SiCo(CO)4 with tetrahydrofuran.Keywords
This publication has 0 references indexed in Scilit: