Chiral Synthesis via Organoboranes. 42. Selective Reductions. 57. Efficient Kinetic Resolution of Representative α-Tertiary Ketones withB-Chlorodiisopinocampheylborane
- 1 January 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 61 (1) , 88-94
- https://doi.org/10.1021/jo951206z
Abstract
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This publication has 35 references indexed in Scilit:
- Chiral synthesis via organoboranes. 34. Selective reductions. 47. Asymmetric reduction of hindered .alpha.,.beta.-acetylenic ketones with B-chlorodiisopinocampheylborane to propargylic alcohols of very high enantiomeric excess. Improved workup procedure for the isolation of product alcoholsThe Journal of Organic Chemistry, 1992
- Synthesis of 2-exo- and 2-endo-mecamylamine analogs. Structure-activity relationships for nicotinic antagonism in the central nervous systemJournal of Medicinal Chemistry, 1991
- Optically active ketones as chiral auxiliaries in the [2,3]-Wittig rearrangementThe Journal of Organic Chemistry, 1991
- Synthesis and absolute configuration of (-)-furodysinin. New transformations of camphor derivativesThe Journal of Organic Chemistry, 1989
- Chemoselective reduction of .BETA.-keto-esters to .BETA.-keto-alcohols.CHEMICAL & PHARMACEUTICAL BULLETIN, 1986
- Studies on antidiabetic agents. IV. Synthesis and activity of the metabolites of 5-(4-(1-methylcyclohexylmethoxy)benzyl)-2,4-thiazolidinedione (ciglitazone).CHEMICAL & PHARMACEUTICAL BULLETIN, 1984
- Stereoselektive Synthese von Alkoholen, VII1) Optisch aktive Homoallylalkohole durch Addition chiraler Boronsäureester an AldehydeEuropean Journal of Inorganic Chemistry, 1981
- Fragmentierungsreaktionen an Carbonylverbindungen mit β‐ständigen elektronegativen Substituenten, XI. Synthese und Konfiguration der 1‐p‐Toluolsulfonyloxy‐2‐methyl‐4‐tert.‐butyl‐2‐formyl‐cyclohexane und 1‐p‐Toluolsulfonyloxy‐2‐methyl‐2‐formyl‐cyclohexane bzw. ‐cyclopentaneEuropean Journal of Inorganic Chemistry, 1969
- The Absolute Configurations of Some Simple Norbornane Derivatives. A Test of the “Conformational Asymmetry” Model1aJournal of the American Chemical Society, 1961
- A New Optically Active Reagent for Carbonyl Compounds; the Resolution of dl-CamphorJournal of the American Chemical Society, 1941