SYNTHESIS OFL-α-CEPHALINS CONTAINING FATTY ACIDS OF SHORTER CHAIN LENGTH: WATER-SOLUBLE GLYCEROLPHOSPHATIDES II
- 1 January 1960
- journal article
- research article
- Published by Canadian Science Publishing in Canadian Journal of Biochemistry and Physiology
- Vol. 38 (1) , 859-864
- https://doi.org/10.1139/y60-106
Abstract
L-[alpha]-(Dihexanoyl)cephalin has been synthesized by the phosphor-ylation of D-[alpha], [beta]-dihexanolglycerol with phenylphosphoryl dichloride and pyridine, esterification of the reaction product, dihexanoyl-L-[alpha] -glycerylphenylphosphoryl chloride, with N-carbobenzoyethanolamine, and simultaneous removal of the protective groups of dlhexanoyl-L-[alpha] -glycerylphenylphosphoryl -N-carbobenzoxyethanolamine by catalytic hydrogenolysis. The L-[alpha]-(dihexanoyl)cephalin is soluble in water. Infrared evidence supports the inner-salt structure of cephalins in chloroform solution.Keywords
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- Synthesis of Enantiomeric α-Cephalins1,2Journal of the American Chemical Society, 1952
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