The unsaturated cyclitol part of the new antibiotics, the validamycins
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 746-747
- https://doi.org/10.1039/c39720000746
Abstract
Microbial degradation of validamycin A gave a new unsaturated aminocyclitol (5) with the 1S-configuration, establishing the structure (1) of the unsaturated cyclitol portion of validamycin A; the structure of epivalidamine (6), a new aminocyclitol derived from dihydrovalidamycin A was also elucidated.Keywords
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