Stacked molecular triangles: self-assembly using coordination chemistry and hydrogen bonding
- 6 December 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 24,p. 2676-2677
- https://doi.org/10.1039/b109784a
Abstract
The combination of the cis-blocked platinum(II) unit (bu2bipy)Pt2+ with the unsymmetrical bis(pyridine) ligand 4-NC5H4C(O)NH-4-C5H4N gives the molecular triangle complex [{Pt(bu2bipy)(μ-4-NC5H4C(O)NH-4-C5H4N)}3]6+, which forms stacked pairs in the solid state through intertriangle NH⋯OC hydrogen bonds and Pt⋯OC secondary bonds.Keywords
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