[Hg3(SCH2CH2S)4]2–and {[Hg2(SCH2CH2S)3]2–}n: examples of trinuclear and quasi-isolated binuclear polymeric mercury thiolate anions
- 1 January 1985
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1498-1499
- https://doi.org/10.1039/c39850001498
Abstract
On varying the reaction conditions, of HgCl2 with ethane-1,2-dithiolate and Ph4PBr in methanol yields either [Ph4P]2[Hg3(SCH2CH2S)4] containing isolated trinuclear anions or [Ph4P]2[Hg2(SCH2CH2S)3] with polymeric anions composed of quasi-isolated binuclear subunits; both mercury thiolates may reflect characteristic structural features of biologically active species.Keywords
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