Thermal explosion and the theory of its initiation by steady intense light
- 8 December 1983
- journal article
- Published by The Royal Society in Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
- Vol. 390 (1799) , 265-281
- https://doi.org/10.1098/rspa.1983.0131
Abstract
The initiation of explosion by steady intense light (from lasers or other sources) involves degradation of the radiation to heat, leading to self-heating and thermal runaway. The critical conditions for such a thermal mechanism can still be expressed in terms of the standard dimensionless group δ = qσ a 0 2 AEexp ( -E/RT a )/ k RT a 2 . When δ attains a critical value δ cr , thermal explosion occurs: the critical value depends on the intensity of the radiation. The dependence of δ cr on the light intensity β is computed numerically for an Arrhenius temperature-dependence of rate. The corresponding critical values for the reduced central temperature-excesses θ 0 , cr are also obtained. If the ambient temperature is too high or the activation energy is too low, so that є = RT a /E is not very small, the phenomenon of criticality disappears. Accurate transitional values for the reduced ambient temperature є tr are calculated as a function of the intensity of the light.This publication has 16 references indexed in Scilit:
- Disappearance of criticality in thermal explosion under frank-kamenetskii boundary conditions: Comment on Zaturska and Gill, Donaldson, and ShoumanCombustion and Flame, 1982
- Exothermic systems with diminishing reaction rates: temperature evolution, criticality and spontaneous ignition in the sphereProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1980
- Thermal explosions and the disappearance of criticality at small activation energies: exact results for the slabProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1979
- The dependence of criticality on activation energy when reactant consumption is neglectedCombustion and Flame, 1978
- Criteria for thermal explosions with and without reactant consumptionProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1977
- Mechanism of initiation of condensed explosives by laser radiationCombustion, Explosion, and Shock Waves, 1969
- Thermal explosions. Part 1.—Induction periods and temperature changes before spontaneous ignitionTransactions of the Faraday Society, 1959
- IntroductionProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1958
- The initiation of explosion by lightProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1958
- Chemical Synthesis of Porphobilinogen: Initiation of Explosion by Light and by Flying FragmentsNature, 1955