Mechanism of methoxyphenylcarbene insertion into Group IV element–hydrogen bonds via a chromium carbene complex
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 578-579
- https://doi.org/10.1039/c39730000578
Abstract
Activation parameters indicate that the first-order component of the kinetic equation corresponds not to complete dissociation of the carbene ligand but rather to the production of an intermediate which is also formed in the kinetically dominant second-order process of the concerted reaction described in the title.Keywords
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