The enantioselective synthesis of marmelo oxides A and B and the assignment of the absolute configurations of marmelo oxides.

Abstract
(+)-Marmelo oxide A and (-)-marmelo oxide B were stereoselectively synthesized from dglutamic acid via (-)-marmelo lactones A and B. The absolute configurations of marmleooxides were thus determined to be the (+)-oxide A having the (2R, 4R) and (+)-oxide B having (2S, 4R) configurations.

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