Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)2, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C6F5)I(PEt3)2
- 4 December 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 2,p. 192-193
- https://doi.org/10.1039/b308741g
Abstract
The reactions of 2,4,6-trifluorophenylboronic acid with aryl(iodo)palladium(II) complexes, trans-Pd(C6F5)I(PR3)2 (PR3 = PEt3, PMe2Ph, PMePh2) in the presence of Ag2O afforded trans-Pd(C6F5)(2,4,6-C6F3H2)(PR3)2 which are stabilized by fluorine atoms in the ortho positions.Keywords
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