‘On–off–on’ fluorescent indicators of pH windows based on three separated components
- 24 September 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 20,p. 2452-2453
- https://doi.org/10.1039/b205951g
Abstract
‘On–off–on’ fluorescent indicators for pH windows are obtained with ternary systems in which the three separated components are Cu2+, a tetraaza ligand and the fluorophore Coumarin 343: protonation of Coumarin 343, its coordination to Cu2+ and its displacement from Cu2+ by OH− give an inverse bell-shaped variation of emission with pH.Keywords
This publication has 8 references indexed in Scilit:
- Signal Amplification by a Fluorescent Indicator of a pH-Driven Intramolecular Translocation of a Copper(II) IonAngewandte Chemie International Edition in English, 2002
- A novel Eu(III)-based luminescent chemosensor: determining pH in a highly acidic environmentTetrahedron Letters, 2001
- Teaching Old Indicators New TricksAccounts of Chemical Research, 2001
- Electrochemically Controlled Assembling/Disassembling Processes with a Bis-imine Bis-quinoline Ligand and the CuII/CuI CoupleChemistry – A European Journal, 1999
- An ‘off-on-off’ fluorescent sensor for pH based on ligand–proton and ligand–metal–proton interactionsNew Journal of Chemistry, 1998
- A fluorescent photoinduced electron transfer sensor for cations with an off-on-off proton switchTetrahedron Letters, 1997
- Investigation of equilibria in solution. Determination of equilibrium constants with the HYPERQUAD suite of programsTalanta, 1996
- Direct visual indication of pH windows: ‘off–on–off’ fluorescent PET (photoinduced electron transfer) sensors/switchesChemical Communications, 1996