Optical Resolutions and Configurations of Benzylmethylphenylsilylmethylamine and Its Derivatives
- 1 March 1980
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 53 (3) , 789-794
- https://doi.org/10.1246/bcsj.53.789
Abstract
New optically active α-amino organosilanes, such as benzylmethylphenylsilylmethylamine, benzylmethyltolylsilylmethylamines, and anisylbenzylmethylsilylmethylamines, were obtained by the fractional crystallization of the salts of the amines and (+)-tartaric acid. Benzylmethylphenylsilylmethylamine was converted into benzylmethyl-1-naphthylphenylsilane, of which the configuration had been known. From these observations, it was found that benzylmethylphenylsilylmethylamine, benzylmethylphenylsilane, and benzylmethoxymethylphenylsilane had S(+), S(−), and S(+) configurations respectively.This publication has 15 references indexed in Scilit:
- Stereochemistry of asymmetric silicon. XXII. Preparation and properties of optically active perfluorophenyl compoundsThe Journal of Organic Chemistry, 1973
- Synthesis, resolution, and absolute configuration of 1-phenyl-1-methyl-1-silacyclohexanone-2Canadian Journal of Chemistry, 1970
- Reactions of Free Silyl Radicals in the Liquid PhaseNippon kagaku zassi, 1970
- Stereochemistry of asymmetric silicon. X. Solvent and reagent effects on stereochemistry crossover in alkoxy-alkoxy exchange reactions at silicon centersJournal of the American Chemical Society, 1968
- Stereochemistry of asymmetric silicon. VIII. Stereochemistry crossover and leaving group basicity in organometallic coupling reactionsJournal of the American Chemical Society, 1967
- Stereochemistry of asymmetric silicon. VII. Silicon-nitrogen bondJournal of the American Chemical Society, 1967
- Stereochemistry of the formation and thermalrearrangement of .beta.-ketosilanesJournal of the American Chemical Society, 1967
- Stereochemistry of Asymmetric Silicon. II. Alkoxy and Siloxy Leaving GroupsJournal of the American Chemical Society, 1964
- The Preparation of Aminomethylsilicon Compounds and their DerivativesJournal of the American Chemical Society, 1951
- Some Interconversion Reactions of Organolithium CompoundsJournal of the American Chemical Society, 1940