The Determination of Molecular Quantities from Measurements on Macroscopic Systems.II. The Determination of Electric Dipole Moments

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Abstract
Some bulk quantities appropriate for the description of dielectric and refractometric measurements on macroscopic systems are defined and their properties are discussed. Based on three molecular models (Lorentz model, Onsager model in spherical approximation, and in ellipsoidal approximation) model molar quantities are introduced, which depend on intrinsic properties of the molecule, i.e. the electric dipole moment and the polarizability. The relations will be applied for the evaluation of the results of dielectric and refractometric measurements on eight aromatic molecules.

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