[TaCl(µ-Cl)(NBut)(NHBUt)(NH2But)]2; a tantalum(V) complex containing terminal imido, amido, and amino ligands
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 205-206
- https://doi.org/10.1039/c39840000205
Abstract
Imido complexes of niobium and tantalum(V) are prepared by the reaction of the pentachlorides with Me3SiNHBut: with excess of t-butylamine, imido, amido, and amino ligands are formed about the same metal centre, as shown in an X-ray crystallographic study of the title complex.Keywords
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