New thermodynamic variables for a nonequilibrium system
- 1 March 1974
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 9 (3) , 1371-1384
- https://doi.org/10.1103/physreva.9.1371
Abstract
The information-theoretic formulation of statistical mechanics is applied to an ideal gas transporting energy without transporting mass. It is shown that the thermal state variables fracture into distinct populations, thus exhibiting a radical sort of local nonequilibrium. The partition function is found in exact form, for an arbitrarily large temperature gradient. In an approximation, it is shown that these results reduce to the known ones for equilibrium, and near equilibrium. The same approximation allows us specific equations for the temperature, pressure tensor, and the entropy of the system, in a far-from-equilibrium case, in terms of the new thermal variables of the system. The general entropy functional, and its variation, are discussed.Keywords
This publication has 19 references indexed in Scilit:
- Nonlinear Heat Conduction in Rarefied Gases Confined between Concentric Cylinders and SpheresPhysics of Fluids, 1972
- Heat-Transfer and Density-Distribution Measurements between Parallel Plates in the Transition RegimePhysics of Fluids, 1968
- Heat Conduction Experiments in Rarefied Gases between Concentric CylindersPhysics of Fluids, 1965
- Heat Transport Between Parallel Plates in a Rarefied Gas of Rigid Sphere MoleculesPhysics of Fluids, 1965
- Kinetic-Theory Description of Conductive Heat Transfer from a Fine WirePhysics of Fluids, 1962
- Application of a Moment Method to Heat Transfer in Rarefied GasesPhysics of Fluids, 1962
- Shear and Heat Flow for Maxwellian MoleculesPhysics of Fluids, 1960
- Heat Flow Between Parallel PlatesPhysics of Fluids, 1959
- Continuum equations in the dynamics of rarefied gasesJournal of Fluid Mechanics, 1959
- Boundary value problems in kinetic theory of gasesAnnals of Physics, 1957