Reaction of a diazepine with chlorodicarbonylrhodium(I) dimer; the molecular structure of chloro-cis-dicarbonyl-(3,5,7-triphenyl-4H-1,2-diazepine)rhodium(I)
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 9,p. 427-428
- https://doi.org/10.1039/c29710000427
Abstract
Chlorodicarbonylrhodium(I) dimer reacts with 3,5,7-triphenyl-4H-1,2-diazepine without cleavage of the N–N bond of the diazepine to yield chloro-cis-dicarbonyl (3,5,7-triphenyl-4H-1,2-diazepine)rhodium(I) in which the diazepine (in a twisted boat conformation) is co-ordinated to the rhodium(I) atom via only one nitrogen atom.Keywords
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