Thermal Decomposition Reactions of Metal Oxalato Complexes in the Solid State. I. Thermographic Studies of Metal Oxalato Complexes
- 1 July 1972
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 45 (7) , 2166-2168
- https://doi.org/10.1246/bcsj.45.2166
Abstract
The thermal decomposition reactions of metal oxalato complexes in the solid state were studied by the TG and DSC methods. The results from TG indicated that the thermal stability of the anhydrous complex decreases approximately with the increase in the electron affinity of the central metal ion. From DSC, the complexes can be divided into two groups, giving endothermic and exothermic peaks on the decomposition of their anhydrous complexes respectively. The two enthalpy changes, ΔH, corresponding to the dehydration and to the decomposition of the anhydrous complexes, are also presented.Keywords
This publication has 10 references indexed in Scilit:
- Thermal decomposition of potassium tris(oxalato)ferrate(III)Inorganic Chemistry, 1971
- The thermal and radiolytic decomposition of K3Mn(C2O4)3. 3H2OInorganic and Nuclear Chemistry Letters, 1970
- The Thermal Decomposition of Potassium Trioxalatoferrate(III) TrihydrateBulletin of the Chemical Society of Japan, 1970
- Kinetics and Mechanisms of Thermal Decomposition Reactions of Cobalt(III) Complexes. Hexammine-, Halogenoammine- and Oxalatoamminecobalt(III) ComplexesBulletin of the Chemical Society of Japan, 1968
- The Thermal Decomposition of Metal Oxalato ComplexesBulletin of the Chemical Society of Japan, 1967
- The thermal decomposition of metal complexes—XVII: Potassium tris(oxalato)manganate(III) trihydrateJournal of Inorganic and Nuclear Chemistry, 1965
- The thermal decomposition of metal complexes—XVIJournal of Inorganic and Nuclear Chemistry, 1965
- The thermal decomposition of metal complexes—I: Thermogravimetric and differential thermal analysis studiesJournal of Inorganic and Nuclear Chemistry, 1961
- Oxalato Complex Compounds of Tervalent ManganeseJournal of the American Chemical Society, 1936
- Über neue dem Sesquioxyd entsprechende VanadinverbindungenZeitschrift für anorganische und allgemeine Chemie, 1899