The first synthesis of a ‘C-disaccharide’
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1353-1354
- https://doi.org/10.1039/c39830001353
Abstract
Condensation of 2,3,4,6-tetrabenzylglucopyranolactone with the anion of methyl 6,7-dideoxy-2,3,4-tri-O-benzyl-α-D-gluco-hept-6-ynopyranoside followed by triethylsilane reduction provided, after hydrogenolysis, the first example of a synthetic β(1 → 6′)-‘C-disaccharide.’Keywords
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