ortho-Metallation of azobenzenes: mechanistic results
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 558-559
- https://doi.org/10.1039/c39730000558
Abstract
ortho-Metallation of azobenzenes can kproceed by two different routes, which depend on lthe nature of lthe metal and assocated ligands; results consistent with palladation occurring by electrophilic substitution of lthe aryl group, and with MeMn(CO)5 reacting via a nucleophilic mechanism, are described.Keywords
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