Reaction of H atoms with some silanes and disilanes. Rate constants and Arrhenius parameters
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 85 (9) , 1447-1463
- https://doi.org/10.1039/f29898501447
Abstract
Arrhenius parameters have been measured for H abstraction by H atoms from the Si—H bond in a number of differently substituted silanes and disilanes. In the case of silane and trimethylsilane kinetic isotope effects have also been determined. The available data on the reactions studied are collated and evaluated, and the trends which emerge are discussed.Keywords
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