Infrared spectrum of the water dimer in solid nitrogen. II. Temperature and irradiation effects
- 1 May 1977
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 66 (9) , 4073-4077
- https://doi.org/10.1063/1.434479
Abstract
The water dimer in solid nitrogen may exist in a stable and a metastable form. Transitions between the two forms are initiated by infrared radiation absorbed by the dimer fundamentals. The metastable form reverts to the stable form by a dark process. D-donating DOH may be transformed into H-donating HOD by infrared radiation. H-donating HOD is metastable and changes back to D-donating DOH by a dark (thermal) process.Keywords
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