Upper and Lower Bounds to Atomic and Molecular Properties. II. Electric Polarizabilities of Four-Electron Atoms by a Lower-Bound Procedure
- 1 November 1973
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 8 (5) , 2231-2235
- https://doi.org/10.1103/physreva.8.2231
Abstract
Wave functions, which include interelectron coordinates explicitly, are employed for the and states of Be I, C III, and O V in obtaining lower bounds and Hylleraas variation-perturbation estimates of dipole polarizabilities for the lowest states of Be I, C III, and O V. Interpolation techniques are used to make a graphical study of the polarizability behavior along the entire isoelectronic sequence. The results of this study are polarizabilities for the lowest state of Be I with probable accuracy ≤ 2%, and the rest of the isoelectronic sequence with probable accuracy of (2-5)%.
Keywords
This publication has 29 references indexed in Scilit:
- Upper and Lower Bounds to Atomic and Molecular Properties. I. Be-Sequence Oscillator Strengths (Dipole-Length Formulation) for theTransitionPhysical Review A, 1973
- Electric polarizabilities of two-electron atoms by a lower-bound procedureProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1972
- Distinguishable Electron Method (DEM) for Electronic Structure Calculations. IV. Polarizability of Three- and Four-Electron AtomsThe Journal of Chemical Physics, 1972
- The static dipole polarizabilities of all the neutral atoms in their ground statesAtomic Data and Nuclear Data Tables, 1971
- Physical properties of many-electron atomic systems evaluated from analytical Hartree-Fock functionsTheoretical Chemistry Accounts, 1968
- Polarizability of the Hydrogen MoleculeThe Journal of Chemical Physics, 1967
- Recent Developments in Perturbation TheoryPublished by Elsevier ,1964
- Alkali Polarizabilities by the Atomic Beam Electrostatic Deflection MethodPhysical Review B, 1963
- Atomic polarizabilities and shielding factorsAdvances in Physics, 1962
- ber den Grundterm der Zweielektronenprobleme von H?, He, Li+, Be++ usw.The European Physical Journal A, 1930