Abstract
A new cyano complex of molybdenum, potassium pentacyano molybdate(IV), KMo(CN)5, has been prepared in three ways : (i) by direct reaction of molybdenum trioxide and potassium cyanide, (ii) by the oxidation of the black heptacyanide, K4Mo(CN)7.2H2O, and (iii) by heating the brown potassium tetracyano dioxo molybdate(IV), K4MoO2(CN)4.

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