Vapour phase photolysis of isocyanic acid
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 64, 911-918
- https://doi.org/10.1039/tf9686400911
Abstract
The vapour-phase photolysis of isocyanic acid has been studied at 30°C. The results have been explained by a mechanism involving alternative primary dissociations of isocyanic acid : [graphic omitted] I1/I2 increases with decreasing wavelength. Subsequent reactions of these radicals lead to the formation of CO, N2, H2 and solid polymer. The gaseous products were formed approximately in the ratio of 3 : 1 : 1.Keywords
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