Cluster size distribution in irreversible aggregation at large times
- 1 October 1985
- journal article
- Published by IOP Publishing in Journal of Physics A: General Physics
- Vol. 18 (14) , 2779-2793
- https://doi.org/10.1088/0305-4470/18/14/028
Abstract
It is assumed that the size distribution ck(t) satisfies Smoluchowski's coagulation equation with rate coefficients K(i, j), behaving as K(i, j) approximately imu jnu (ik(t) approaches for t to infinity the exact solution Cbk/t(k=1, 2, . . .), where the bk's are independent of the initial conditions ck(0), and can be determined from a recursion relation. In class II systems ( mu =0), ck(t)/c1(t) to bk (t to infinity , k=1, 2, . . .), but the bk's depend on ck(0). Only in the scaling limit (k to infinity , s(t) to infinity with k/s(t)=finite; s(t) is the mean cluster size) does ck(t) approach a form independent of the initial distribution. Class III, where ck(t)/c1(t) to infinity (t to infinity , k=2, 3, . . .), has not been considered here.Keywords
This publication has 8 references indexed in Scilit:
- Dynamic Scaling in the Kinetics of ClusteringPhysical Review Letters, 1985
- Large-time behavior of the Smoluchowski equations of coagulationPhysical Review A, 1984
- Coagulation processes with a phase transitionJournal of Colloid and Interface Science, 1984
- Kinetics of gelation and universalityJournal of Physics A: General Physics, 1983
- Critical kinetics near the gelation transitionJournal of Physics A: General Physics, 1982
- Critical Properties for Gelation: A Kinetic ApproachPhysical Review Letters, 1982
- Critical kinetics near gelationJournal of Physics A: General Physics, 1982
- On the form of steady-state solutions to the coagulation equationsJournal of Colloid and Interface Science, 1982