On the Coupling between Electronic and Nuclear Motion and Van der Waals' Interaction between Helium Atoms
- 1 February 1956
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 24 (2) , 444-446
- https://doi.org/10.1063/1.1742494
Abstract
The analytical expression for the potential due to the coupling between the electronic and the nuclear motion for two normal helium atoms has been obtained for a wave function of the form of that of P. Rosen. This coupling interaction is a repulsive potential and is to be added to the usual ``valence'' and Van der Waals' potential obtained in the static-nuclei approximation. This coupling interaction, being inversely proportional to the reduced mass of the two interacting atoms, contributes to a weaker binding between two He3 atoms than between two He4 atoms.Keywords
This publication has 2 references indexed in Scilit:
- On the Coupling Between Electronic and Nuclear Motions in MoleculesThe Journal of Chemical Physics, 1956
- The Repulsive Potential of Normal Helium AtomsThe Journal of Chemical Physics, 1950