An Improved Procedure for the Conversion of Alkenes and Glycals to 1,2-Diazides Using Mn(OAc)3·2H2O in Acetonitrile Containing Trifluoroacetic Acid
- 1 May 1998
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 28 (10) , 1913-1922
- https://doi.org/10.1080/00397919808007024
Abstract
Alkenes and Glycals react with Mn(OAc3)·2H2O and NaN3 in 9:1 acetonitrile-trifluoroacetic acid to give 1,2-diazides in >80% yield. Allylic azides are formed by slow addition of NaN3 to a mixture of alkene, Mn(OAc)3·2H2O and Cu(OAc)2.Keywords
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