Growth and Agglomeration of Particles in Low-Temperature GR-S Type of Latex

Abstract
It has been shown that it is possible to prepare high-solids latex by polymerizing to an intermediate solids content and particle size, followed by solvent agglomeration and concentration. It has also been shown that a somewhat similar agglomeration normally takes place at intermediate conversions in conventional high-solids latex recipes. The slow rates of polymerization in the latter recipes after agglomeration are primarily due to the greatly reduced number of particles present. The ratio of hydrocarbon to water is very important in determining the extent of agglomeration both during and after polymerization.