Absolute configuration of tylophorine
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1161-1165
- https://doi.org/10.1039/p19740001161
Abstract
The configuration at C-13a in tylophorine (I) has been established as S. Ozonolysis of tylophorine gave (S)-pyrrolidine-2-acetic acid identical with a sample synthesized from (S)-proline. The absolute configuration of analogous alkaloids of the group can be deduced by comparison of their o.r.d. spectra with that of tylophorine.Keywords
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