The dissociation energy of F^-and the stability of alkali perfluorides

1 January 1971

journal article
research article
Published by Taylor & Francis in Molecular Physics

Vol. 21 (2) , 193-207
https://doi.org/10.1080/00268977100101341

Abstract

Multiconfiguration valence bond calculations using accurate AO bases have been carried out for F₂ and F₂ ^-. A dissociation energy of at least 1·06 eV is predicted for the F₂ ^- ion. Lattice energy calculations together with this value lead to an approximate value of ΔG = -16 kcal mole^-1 for the reaction The true value may be much closer to zero.

Keywords

This publication has 15 references indexed in Scilit:

Open-shell valence configuration-interaction studies of diatomic and polyatomic molecules
International Journal of Quantum Chemistry, 2009
Reply to Comments by Prosser and Hagstrom Concerning Corresponding Orbitals and Cofactors
The Journal of Chemical Physics, 1968
Extended Hartree—Fock Wavefunctions: Optimized Valence Configurations for H2 and Li2, Optimized Double Configurations for F2
The Journal of Chemical Physics, 1966
Thermodynamics of the Higher Oxides. I. The Heats of Formation and Lattice Energies of the Superoxides of Potassium, Rubidium, and Cesium¹
The Journal of Physical Chemistry, 1965
Atomic polarizabilities and shielding factors
Advances in Physics, 1962
Lattice Energies and their Significance in Inorganic Chemistry
Published by Elsevier ,1959
Optical Absorption of ${Cl}_{2}^{-}$ Molecule-Ions in Irradiated Potassium Chloride
Physical Review B, 1958
The dissociation energy of fluorine
Transactions of the Faraday Society, 1958
Atoms in molecules and crystals
Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1951
THE RAMAN SPECTRUM OF FLUORINE
Canadian Journal of Physics, 1951

The dissociation energy of F-and the stability of alkali perfluorides

Abstract

Keywords

The dissociation energy of F^-and the stability of alkali perfluorides