The solid-phase reaction [60]fullerene: novel addition of organozinc reagents
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 17,p. 2059-2060
- https://doi.org/10.1039/cc9960002059
Abstract
Reaction of ethyl bromoacetate and zinc with [60]fullerene in the absence of any solvent, followed by quenching with acid affords 1-ethoxycarbonylmethyl-1-20 dihydro [60]fullerene along with other minor byproducts including 1,4-bis(ethoxycarbonylmethyl)-1,4-dihydro[60]fullerene; a detailed reaction mechanism is proposed.Keywords
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