[Fe3S(S2C10H12)3]2−: The First Synthetic Trinuclear Iron‐Sulfur Cluster Compound
- 1 December 1981
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 20 (12) , 1033-1034
- https://doi.org/10.1002/anie.198110332
Abstract
In the first model for trinuclear iron‐sulfur centers in recently discovered proteins—namely, the central FeS7 moiety in [(C2H5)4N][Fe3S7C30H36]·CH3OH—the Fe atoms from a completely bonded triangle and are each surrounded by a tetrahedron of S atoms which is somewhat distorted from idealized symmetry and consists of an inorganic S atom above the center of the metal triangle and three mercapto S atoms, two of which form slightly asymmetric bridges to neighboring Fe atoms.Keywords
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