Photocyclization Reactions of Aryl Polyenes. V. Photochemical Synthesis of Substituted Chrysenes

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Abstract
The photocyclization-oxidation reaction of 1,6-di-p-substituted-phenyl-1,3,5-hexatrienes gave 3,9-disubstituted-chrysenes. Similarly, irradiation of 1-p-substituted-phenyl-6-phenyl-1,3,5-hexatrienes yielded 3-substituted-chrysenes. The 3-substituted-chrysenes were independently prepared in a high yield by the photocyclization-oxidation of 1-α-naphthyl-2-p-substituted-phenylethylenes.

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