NMR relaxation study of Li+–Ni2+ interaction in aqueous solution

15 December 1980

journal article
research article
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 73 (12) , 6031-6038
https://doi.org/10.1063/1.440137

Abstract

The NMR relaxation of 7Li+ due to Ni2+ in aqueous solution as a function of magnetic field strength is experimentally determined and is calculated on tha basis of certain models for the ionic interactions. The results can be used to eliminate some models which are consistent with the osmotic coefficient data for aqueous LiCl, NiCl2, and their mixtures.

Keywords

This publication has 28 references indexed in Scilit:

An oxygen-17 nuclear magnetic resonance study of the aquo nickel(II) sulfate system
The Journal of Physical Chemistry, 1978
Analysis of the total ion–solvent encounter configurations of CIO–4 and BF–4 with Na⁺and Li⁺in water, studied by various nuclear magnetic relaxation times
Faraday Discussions of the Chemical Society, 1977
Ionic solution theory for non-ideal solvents. Potential of mean force between ions
Faraday Discussions of the Chemical Society, 1977
Large perturbations and nonexponential decays in spin relaxation. Applications of the memory function theory
The Journal of Chemical Physics, 1976
The Ursell-function structure of the memory function
The Journal of Chemical Physics, 1975
Charge-asymmetric mixtures of electrolytes at low ionic strength
The Journal of Physical Chemistry, 1974
Investigation of the hydrophobic interaction between tert-butyl alcohol and paramagnetic solutes in aqueous solutions by proton nuclear magnetic resonance relaxation
The Journal of Physical Chemistry, 1974
Polar solvent structure in the theory of ionic solvation
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1974
Intermolecular nuclear relaxation and molecular pair distribution in liquid mixtures
Published by Walter de Gruyter GmbH ,1972
Nuclear Spin–Lattice Relaxation in LiCl Solutions
The Journal of Chemical Physics, 1968