Novel Easy Preparations of Some Aromatic Iodine(I, III, and V) Reagents, Widely Applied in Modern Organic Synthesis
Open Access
- 30 January 2003
- Vol. 8 (1) , 45-52
- https://doi.org/10.3390/80100045
Abstract
We report our novel (or considerably improved) methods for the synthesis of aromatic iodides, (dichloroiodo)arenes, (diacetoxyiodo)arenes, [bis(trifluoroacetoxy)-iodo]arenes, iodylarenes and diaryliodonium salts, as well as some facile, oxidative anion metatheses in crude diaryliodonium or tetraalkylammonium halides and, for comparison, potassium halides. All our formerly published papers were discussed and explained in our review “Organic Iodine(I, III, and V) Chemistry: 10 Years of Development at the Medical University of Warsaw, Poland” (1990-2000) [1]. Our newest results are discussed below.Keywords
This publication has 12 references indexed in Scilit:
- Microwave-Accelerated Iodination of Some Aromatic Amines, Using Urea-Hydrogen Peroxide Addition Compound (UHP) as the OxidantMolecules, 2002
- Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the OxidantMolecules, 2002
- Easy Preparation of (Diacetoxyiodo)arenes from Iodoarenes with Sodium Percarbonate as the OxidantMolecules, 2002
- One-Pot Preparations of (Dichloroiodo)arenes from Some ArenesBulletin of the Chemical Society of Japan, 2001
- Some Heteroaromatic Organomercurials, Their Syntheses and Reactions: A Review of Our Research (1980-2000)Molecules, 2001
- Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the OxidantMolecules, 2001
- One-Pot Preparations of Diaryliodonium Bromides from Iodoarenes and Arenes, with Sodium Perborate as the OxidantMolecules, 2001
- One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the OxidantMolecules, 2001
- Organic Iodine(I, III, and V) Chemistry: 10 Years of Development at the Medical University of Warsaw, PolandMolecules, 2000
- Further functional group oxidations using sodium perborateTetrahedron, 1989