The First Coordinatively Saturated, Quadruply Stranded Helicate and Its Encapsulation of a Hexafluorophosphate Anion.
- 17 December 1998
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 37 (23) , 3295-3297
- https://doi.org/10.1002/(sici)1521-3773(19981217)37:23<3295::aid-anie3295>3.0.co;2-5
Abstract
Incarcerated in a helical prison: The encapsulation of a PF6− ion within a quadruply stranded helicate (shown schematically) results from the self-assembly of four molecules of 1,4-bis(3-pyridyloxy)benzene and two PdII ions. This represents not only the first example of a coordinatively saturated quadruple helicate, but also the first example of the encapsulation of a complex anion by a helicate.Keywords
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