Acetylenic derivatives of [Fe2(CO)6(µ-Se2)]: acetylenic bond reduction on a selenium-stabilised Fe2Pt mixed-metal complex
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 46-48
- https://doi.org/10.1039/c39930000046
Abstract
Stepwise addition of phenylacetylene and Pt(PPh3)2across the Se–Se bond of [Fe2(CO)6(µ-Se2)] can be carried out at room temperature; X-ray analysis demonstrates the acetylenic carbon–carbon bond reduction in the mixed-metal complex [(CO)6Fe2Pt(PPh3)2{µ-SeC(Ph)C(H)Se}].Keywords
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