The Valence Tautomerism of Cyclooctatetraene
- 1 February 1964
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 3 (2) , 83-85
- https://doi.org/10.1002/anie.196400831
Abstract
The Diels‐Alder adducts of cyclooctatetraene and its derivatives are derived from the bicyclo[4,2,0]octane structure. A kinetic investigation shows that the Diels‐Alder addition of dienophiles to cyclooctatetraene and phenylcyclooctatetraene is preceded by a valence tautomerism equilibrium with bicyclo[4,2,0]octa‐2,4,7‐triene or its 7‐phenyl derivative.This publication has 14 references indexed in Scilit:
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