Room-temperature reactions of CsSO4F with organic molecules containing heteroatoms
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 563-564
- https://doi.org/10.1039/c39830000563
Abstract
Room-temperature fluorination of pentane-2,4-dione with CsSO4F gave 3-fluoro and 1,3-difluoro derivatives, while 5,5-difluorobarbituric acid was formed in high yield in a 2 h reaction at 100 °C; 1,3-dimethyluracil was converted in methanol via cis- and trans-5-fluoro-6-methoxy derivatives into 5-fluoro-1,3-dimethyluracil in high yield and uridine into 5-fluorouridine.Keywords
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