Intra- and Intermolecular H/D Exchange in Aqueous Solution Catalyzed by Molybdocenes
- 6 August 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (16) , 2406-2408
- https://doi.org/10.1002/(sici)1521-3773(19990816)38:16<2406::aid-anie2406>3.0.co;2-1
Abstract
C−H bond activation in water catalyzed by water‐soluble molybdocene complexes results in H/D exchange in alcohols [Eq. (1)]. Deuterium is incorporated intramolecularly in the Cp′ methyl group of the metallocene as well as intermolecularly on the α‐carbon atoms of the alcohols at moderate temperatures (Cp′=η5‐C5H4CH3).Keywords
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