Sustained catalytic homogenous oxo-transfer oxidation of alkanes. Interaction of alkyl hydroperoxides with transition metal-substituted polyoxometalates
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1487-1489
- https://doi.org/10.1039/c39870001487
Abstract
The oxo-transfer oxidation of alkanes by t-butyl hydroperoxide can be catalysed by particular transition metal-substituted heteropolytungstates; the product yields and the stabilities of these systems are higher than those of other homogenous catalytic alkane oxygenation systems reported in the literature.Keywords
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