Some hydrido(aryl)bis-(π-cyclopentadienyl)tungsten and related compounds
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1508-1511
- https://doi.org/10.1039/j19710001508
Abstract
The hydrido(aryl)tungsten compounds (π-C5H5)2WH(R)(R = Ph, C6D5, or p-C6H4Me) have been prepared from benzene, deuteriobenzene, or toluene by reaction with the dihydride (π-C5H5)2WH2in the presence of a conjugated diene. The aryl hydrides (π-C5H5)2WH(R)(R = Ph or p-C6H4Me) react with halocarbons giving the halogeno(aryl)tungsten compounds (π-C5H5)2WX(Ph)(X = Cl, Br, or l) or (π-C5H5)2WCl(p-C6H4 Me).Keywords
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