Syntheses and Reactions of Metal Organics. XIV. Syntheses of Fluoroalkyl Silicates
- 1 June 1990
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 20 (6) , 729-741
- https://doi.org/10.1080/00945719008048169
Abstract
The new compounds, tetrakis(1H, 1H, 3H-perfluoropropyl) silicate, Si(OCH2CF2CF2H)4, tetrakis(1H, 1H, 5H-perfluoropentyl) silicate, Si[OCH2(CF2CF2)2H]4, tetrakis(1H, 1H, 7H-perfluoroheptyl) silicate, Si[OCH2(CF2CF2)3H]4 and tetrakis-(1H, 1H, 9H-perfluorononyl) silicate, Si[OCH2(CF2CF2)4H]4, were prepared by the reaction of silicon tetrachloride with fluoro-substituted alcohols in the presence of ammonia. The 1H, 13C, 19F NMR and IR spectral data of these silicates were obtained.Keywords
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