Ready formation of a Bredt compound, tricyclo[5,3,1,03,8]undec-2-ene. conformational preference leading to regiospecificity in a planar cis-elimination
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 372-373
- https://doi.org/10.1039/c39750000372
Abstract
Dehydrobromination of 3,9-ethanobicyclo[3,3,1]-non-l-yl (tricyclo[5,3,1,03,8]undec-3-yl) bromide (I) with sodium amide in refluxing toluence gave 3,9-ethanobicyclo[3,3,1]non-1-ene (tricyclo[5,3,1,03,8]undec-2-ene)(II) in 52% yield.Keywords
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